Rank the following compounds in order of increasing reactivity (least reactive first) in an SN1 solvolysis reaction
Question:
(1) m-nitro-terfrcumyl chloride
(2) p-methoxy-terfrcumyl chloride
(3) p-fluoro-terr-cumyl chloride
(4) p-nitro-terfrcumyl chloride
Table 17.2
Transcribed Image Text:
TABLE 17.2 Comparison of S 1 Solvolysis Rates of Benzylic and Nonbenzylic Alkyl Halides Comparison of SN1 Solvolysis Rates of Benzylic and Nonbenzylic Alkyl Halides R-Cl + H2O 25°C 90% aqueous acetone R-OH + HCl Relative rate Alkyl chloride R-CI (CHCC Ph-CH-C Common name tert-butyl chloride o-phenethyl chloride 1.0 CH3 CH Ph-C-I tert-cumyl chloride 620 CH3 Ph,CH CI Ph,C-C benzhydryl chloride 200 trityl chloride >600,000 n 80% aqueous ethanol.
Fantastic news! We've Found the answer you've been seeking!
Step by Step Answer:
Answer rating: 91% (12 reviews)
The compounds that give the most stable carbocation intermediates are the ones that undergo the most ...View the full answer
Answered By
Rishabh Ojha
During my undergraduate i used to participate as TA (Teaching Assistant) in several electronics and computers subject. I'm passionate about learning Computer Science as my bachelors are in Electronics but i learnt most of the Computer Science subjects on my own which Machine Learning also. At Present, i'm a working professional pursuing my career as a Machine Learning Engineer and i want to help others learn during my free hours, that's all the motivation behind giving tuition. To be frank i have no prior experience of tutoring but i have solved problems on opensource platforms like StackOverflow and github. ~Thanks
4.90+
3+ Reviews
10+ Question Solved
Related Book For
Question Posted:
Students also viewed these Organic Chemistry questions
-
Rank the following compounds in order of increasing reactivity in bromination. In each case, indicate whether the principal monobromination products will be the ortho and para isomers or the meta...
-
Rank the following compounds in order of increasing reactivity toward nitration with HNO3 and explain your choices: thiophene, benzene, 3-methylthiophene, and Z-methvlfuran.
-
Rank the following compounds in order of increasing reactivity toward electrophilic aromatic substitution: Br Br- Br
-
Assuming that the Fed judges inflation to be the most significant problem in the economy and that it wishes to employ all of its policy instruments except interest on reserves, what should the Fed do...
-
Farmers in an arid region in Mexico draw their irrigation water from an underground aquifer. The aquifer has a natural maximum recharge rate of 340 gallons per day (that is 340 gallons per day filter...
-
On July 1, 2012, Philip Ward bought a used pickup truck at a cost of $5,300 for use in his business. On the same day, Ward had the truck painted blue and white (his companys colors) at a cost of...
-
In 2002, the FASB concluded that the amortization of goodwill should no longer be required, and instead that goodwill be subject to an annual impairment test to verify that its value had not...
-
Clarabelles Construction is analyzing its capital expenditure proposals for the purchase of equipment in the coming year. The capital budget is limited to $ 10,000,000 for the year. Laura Bobo, staff...
-
You buy a pair of jeans at a store, at a sale price of $100. The store paid $40 to its supplier for the pair of jeans. What is the net income for the store? Select an answer: 100 70 60 40
-
Consider the following parlor game to be played between two players. Each player begins with three chips: one red, one white, and one blue. Each chip can be used only once. To begin, each player...
-
Outline a synthesis of each of the following compounds from the indicated starting materials and any other reagents. (a) Benzyl methyl ether from toluene (b) (c) (d) CH2CH O from cyclopentene 7-CO.H...
-
Explain why compound A reacts faster than compound B when they undergo solvolysis in aqueous acetone. CH C-Cl CH3 CH CH
-
Match the situation with the graph (a-d) that models it best, where x-values represent time. Height of the Empire State Building from 1990 to 2010 a. y b. y d.
-
what ways do hierarchical organizational structures influence decision-making efficiency and employee autonomy, and how might these factors affect innovation and adaptability in a rapidly changing...
-
Customer Relationship Marketing (CRM) calls for a robust approach that eclipses a 360 view of the customer through development, growth and maintenance of long term cost effective relationships with...
-
How do social movements mobilize collective action and challenge dominant power structures to effect social change and promote social justice ?
-
Thalassines Kataskeves, S.A., of Greece makes marine equipment. The company has been experiencing losses on its bilge pump product line for several years. The most recent quarterly contribution...
-
What are the implications of postcolonial theory for understanding the legacies of colonialism and ongoing processes of decolonization in globalized societies ?
-
Perform the indicated operations assuming all numbers are approximate and round the answer appropriately. 35.78 22.944 + 5.1
-
What are the six activities involved in the physical supply/distribution system?
-
Write a Lewis structure for each of the following: (a) SOCl2 (b) POCl3 (c) PCl5 (d) HONO2 (HNO3)
-
Give the formal charge (if one exists) on each atom of the following: (a) (b) (c) (d) CH3-S CH3 CH-S-O:
-
Add any unshared electrons to give each element an octet in its valence shell in the formulas below and indicate any formal charges. All of the hydrogen atoms that are attached to heteroatoms have...
-
22 (1 point) Single materiality is a reporting approach that accounts for how sustainable factors affect the financial value of a firm. 1. True 2. False
-
Current Attempt in Progress Blossom, a chain of candy stores, purchases its candy in bulk from its suppliers. For a recent shipment, the company paid $3000 and received 7200 pieces of candy that are...
-
Rephrase. pcG STATED SHE HAD NOT BEEN FULLY HONEST AND THAT TTHEY SOLE THERE MOTHER HOME AND COULD NOT USE MEDICAID AS A BENEFIT BUT THE PROCEEDS FROM SELLING THE HOME WAS SOLEY TO BE USE TO CARE FOR...
Study smarter with the SolutionInn App