In this chapter, from the third law of thermodynamics, it has been shown that the entropy of
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In this chapter, from the third law of thermodynamics, it has been shown that the entropy of all substances approaches a common value at 0 K (which for convenience we have taken to be zero). This implies that the value of the entropy at 0 K is not a function of volume or pressure. Use this information to show the following:
CV = 0
at T = 0K and that the coefficient of thermal expansion
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is zero at 0 K. a= a 1 + (*), V P
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Proof that CV 0 at T 0K Given that the entropy of all substances approaches a common value at 0 Kwe ...View the full answer
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Related Book For
Chemical Biochemical And Engineering Thermodynamics
ISBN: 9780470504796
5th Edition
Authors: Stanley I. Sandler
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