Substitution of H 2 O in [Fe(OH 2 ) 6 ] 3+ by thiocyanate is complicated by

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Substitution of H2O in [Fe(OH2)6]3+ by thiocyanate is complicated by proton loss. By considering the reaction scheme below, derive an expression for

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in terms of the equilibrium and rate constants, [Fe(OH2)63+], [SCN], [Fe(OH2)5(SCN)2+] and [H+].

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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