Use the data in Table 9.2 to assign the Q branch lines in Figure 9.6. Account for
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Use the data in Table 9.2 to assign the Q branch lines in Figure 9.6. Account for the relative intensities.
Figure 9.6
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Table 9.2 Spectroscopic constants for diatomics in the ground electronic state V₁, cm-1 x₂v₂, cm-1 B₁, cm-1 αe, cm-1 R₂, Å 11.67 1.6326 0.01683 1.3117 13.46 1.9313 0.01896 1.1281 2.993 0.7416 0.3019 1.2746 0.000117 2.6666 0.01731 1.094 0.01579 0.714 12C2 12C160 ¹H₂ 1H35CI 1641.35 2170.21 4395.20 117.9 2989.74 52.05 214.57 2359.61 14.456 1580.36 12.073 82.81 12712 14N₂ 1602 160¹H 3735.21 0.6127 60.80 10.59 0.03735 1.998 1.4456 18.871 1.20739 0.9706 Do, ev 3.6 10.96 4.476 4.430 1.5417 7.373 5.080 4.35
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In IR spectroscopy the Q branch represents transitions where there is no change in the rotational quantum number AJ 0 This means that the observed lin...View the full answer
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