Which nitrogen atom in imidazole (Problem 12.16) is more basic according to the following electrostatic potential map?

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Which nitrogen atom in imidazole (Problem 12.16) is more basic according to the following electrostatic potential map? Why?image


Problem 12.16

The five-membered heterocycle imidazole contains two nitrogen atoms, one “pyrrole-like” and one “pyridine-like.” Draw an orbital picture of imidazole, and indicate the orbital in which each nitrogen has its electron lone pair.image

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