According to Equation 9.30, the vibrationrotation constant for a harmonic oscillator is not zero and is in
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According to Equation 9.30, the vibration–rotation constant for a harmonic oscillator is not zero and is in fact negative. Consider the rotational constant for the v = 0 state of a harmonic oscillator, which is proportional to the expectation value {1/R}V = 0. Show that this expectation value is greater than 1/R2e, thus B0 for a harmonic oscillator is greater than Be, resulting in a negative vibration–rotation coupling constant.
Equation 9.30
Transcribed Image Text:
de -2B²2B₂RV(3) 2B, R/V + 3} +3 hv² Ve
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The equation provided represents the vibrationrotation interaction constant a for a diatomic molecul...View the full answer
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