In applying the Numerov method to count the nodes in r, we assumed that changes sign
Question:
(a) Use the Schrödinger equation to show that if ψ(x) = 0 at x = a, then ψ = 0 at x = a (provided V(a) ≠ ∞).
(b) Differentiate the Schrödinger equation to show that if both ψ and ψ are zero at x = a, then ψ"'(a) = 0 [provided V' (a) ≠ ∞]. Then show that all higher derivatives of ψ are zero at x = a if both ψ and ψ are zero at x = a (and no derivatives of V are infinite at x = a). If ψ and all its derivatives are zero at x = a, the Taylor series (4.85) shows that ψ is zero everywhere. But a zero function is not allowed as a wave function. Therefore, ψ and ψ cannot both be zero at a point, and the wave function must have opposite signs on the two sides of a node.
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