Isopropanol, containing 13 wt% water, can be dehydrated to obtain almost pure isopropanol at a 90% recovery
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Isopropanol, containing 13 wt% water, can be dehydrated to obtain almost pure isopropanol at a 90% recovery by azeotropic distillation with benzene. When condensed, the overhead vapor from the column splits into two immiscible liquid phases. Use the relations in Table 2.4 with data in Perry's Handbook and the operating conditions below to compute the rate of heat transfer in Btu/h and kJ/h for thecondenser.
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Organic- Water-Rich Rich Overhead Phase Phase Phase Temperature. "C Pressure, bar Flow rate, kg/h: Isopropanol Water Vapor 76 Liquid 40 Liquid 40 1.4 1.4 1.4 5,870 1,790 6,800 2,350 24,600 930 560 Benzene 24,570 30 Ideal gas and ideal-gas solution: RT M = y, M, (1) vy = Pv i-1 ΣΜ i=) (2) hv Σn (c ) ar- Συ !3! (Chv ΣΚ9 (3) sv dT R In Po y In y where the first term is s Ideal-liquid solution: -ΣΜ M = (4) VL = PL ΣΜ. (5) h Σκ (,-ΔΗ) %3D ΔΗ dT (C)v ΣΚ. (6) S1 To i=1 R in ()-RE* In.xi -R In Po Vapor-liquid equilibria: (7) K; =
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