Question: The virial equation for a binary mixture is Here B 11 and B 22 are the second virial coefficients for pure species 1 and pure
The virial equation for a binary mixture is

Here B11 and B22 are the second virial coefficients for pure species 1 and pure species 2, respectively, and B12 is the cross second virial coefficient. For a binary mixture
a. Obtain an expression for the fugacity coefficient of a species (Eq. 9.4-6).

b. Show that the activity coefficient for species 1 is
![]()
where δ12 = 2B12 − B11 − B22.
c. Generalize the results in part (b) to a multicomponent mixture
with PV RT 1+ Bmix V + Bmix = yB1 + y2B22 + 2y1y2B12
Step by Step Solution
3.34 Rating (154 Votes )
There are 3 Steps involved in it
Get step-by-step solutions from verified subject matter experts
