For the reaction A 2 B C D, the rate law is rate of reaction k A B (a) Show that the following mechanism is consistent with the stoichiometry of the overall reaction and with the rate law (b) Show that the following mechanism is consistent with the stoichiometry of the overall reaction, but not with the rate law A BI (slow) I B C D (fast)

Question: For the reaction A + 2 B C + D, the rate law is rate of reaction = k[A][B]. (a) Show that the following

For the reaction A + 2 B → C + D, the rate law is rate of reaction = k[A][B].

(a) Show that the following mechanism is consistent with the stoichiometry of the overall reaction and with the rate law.

A+BI (slow) I + B C + D (fast)

(b) Show that the following mechanism is consistent with the stoichiometry of the overall reaction, but not with the rate law.

2 B A + B B (fast) k-1 k2 C + D (slow)

A+BI (slow) I + B C + D (fast)

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