The reaction 2 NO + 2 H 2 N 2 + 2 H 2 O is

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The reaction 2 NO + 2 H→ N2 + 2 H2O is second order in [NO] and first order in [H2]. A three-step mechanism has been proposed. The first, fast step is the elementary process given as equation (20.25). The third step, also fast, is N2O + H→ N2 + H2O. Propose an entire three-step mechanism, and show that it conforms to the experimentally determined reaction order.

Eq. 20.25

Fast: k k1 2 NO(g) NO(g) (20.25)

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General Chemistry Principles And Modern Applications

ISBN: 9780132931281

11th Edition

Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette

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