(a) Draw possible stereoisomers for the trigonal bipyramidal [SiF 3 Me 2 ] anion (Me =...

Question:

(a) Draw possible stereoisomers for the trigonal bipyramidal [SiF3Me2] anion (Me = CH3). An X-ray diffraction study of a salt of [SiF3Me2] shows that two F atoms occupy axial sites. Suggest why this stereoisomer is preferred over the other possible structures that you have drawn.

(b) Account for the fact that members of the series of complexes [PtCl4]2−, [PtCl3(PMe3)], [PtCl2(PMe3)2] and [PtCl(PMe3)3]+ do not possess the same number of stereoisomers.

Fantastic news! We've Found the answer you've been seeking!

Step by Step Answer:

Related Book For  book-img-for-question

Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

Question Posted: