A neutral macrocyclic ligand with four donor atoms produces a red diamagnetic low-spin d 8 complex of

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A neutral macrocyclic ligand with four donor atoms produces a red diamagnetic low-spin d8 complex of Ni(II) if the anion is the weakly coordinating perchlorate ion. When perchlorate is replaced by two thiocyanate ions, SCN, the complex turns violet and is high-spin with two unpaired electrons. Interpret the observed change in terms of the structure of the complexes.

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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