For a [4Fe4S] protein, the following series of redox reactions are possible; each step is a 1-electron
Question:
For a [4Fe–4S] protein, the following series of redox reactions are possible; each step is a 1-electron reduction or oxidation:
(a) Which of these couples are accessible under physiological conditions?
(b) Which couple represents the HIPIP system?
(c) How do the redox potentials of the HIPIP and [4Fe–4S] ferredoxin system differ and how does this affect their roles in the mitochondrial electron-transfer chain?
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a The redox reactions that are accessible under physiological conditions are those that involve redox potentials suitable for biological electron transfer processes Typically redox reactions with mode...View the full answer
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