In the gas phase, the base strength of amines increases regularly along the series NH 3 <

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In the gas phase, the base strength of amines increases regularly along the series NH3 < CH3NH2 < (CH3)2NH < (CH3)3N. Consider the role of steric effects and the electron-donating ability of CH3 in determining this order. In aqueous solution, the order is reversed. What solvation effect is likely to be responsible?

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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