Rationalize the following signal multiplicities in the 119 Sn NMR spectra of some halo-anions and, where possible,

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Rationalize the following signal multiplicities in the 119Sn NMR spectra of some halo-anions and, where possible, use the data to distinguish between geometric isomers [19F 100% I = 1/2]: 

(a) [SnCl5F]2− doublet; 

(b) [SnCl4F2]2− isomer A, triplet; isomer B, triplet; 

(c) [SnCl3F3]2− isomer A, doublet of triplets; isomer B, quartet; 

(d) [SnCl2F4]2− isomer A, quintet; isomer B, triplet of triplets; 

(e) [SnClF5]2− doublet of quintets; 

(f) [SnF6]2− septet.

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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