The ambidentate thiocyanate ligand (SCN ) can coordinate to a metal centre either through sulfur (SCN)
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The ambidentate thiocyanate ligand (SCN−) can coordinate to a metal centre either through sulfur (SCN) or nitrogen (NCS), Chapter 7. Explain the following observed vibrational frequencies for the C–S bond (ν(CS)): K2[Co(SCN)4].4H2O, 850 cm−1; KSCN, 746 cm−1; K2[Pd(SCN)4], 730 cm−1. RbBi(SCN)4 shows an absorption in its IR spectrum at 722 cm−1; what is the likely mode of bonding of the thiocyanate group to bismuth in this compound?
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The vibrational frequencies of the CS bond CS in different complexes containing the ambidentate thio...View the full answer
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Related Book For 
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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