The complex first denoted -[PtCl 2 (NH 3 ) 2 ] was identified as the trans isomer.
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The complex first denoted β-[PtCl2(NH3)2] was identified as the trans isomer. (The cis isomer was denoted α.) It reacts slowly with solid Ag2O to produce [Pt(NH3)2(OH2)2]2+. This complex does not react with 1,2-diaminoethane to give a chelated complex. Name and draw the structure of the diaqua complex. A third isomer of composition PtCl2·2NH3 is an insoluble solid that, when ground with AgNO3, gives a mixture containing [Pt(NH3)4] (NO3)2 and a new solid phase of composition Ag2[PtCl4]. Give the structures and names of each of the three Pt(II) compounds.
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Lets start by naming and drawing the structures of the three PtII compounds mentioned in the questio...View the full answer
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Related Book For 
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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