The EPR spectrum of bis[tris(2-pyridyl)methane]copper(II) dinitrate is isotropic at 293 K, but is axial with g

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The EPR spectrum of bis[tris(2-pyridyl)methane]copper(II) dinitrate is isotropic at 293 K, but is axial with g > g⊥ at 150 K. Explain these observations by references to the EPR timescale and dynamic Jahn–Teller distortions that can occur in copper complexes.

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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