Two complexes that have entered clinical trials as anti-cancer drugs are [HIm][RuCl 4 (im)(DMSO)] and [HInd][RuCl 4
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Two complexes that have entered clinical trials as anti-cancer drugs are [HIm][RuCl4(im)(DMSO)] and [HInd][RuCl4(Ind)2]. In the search for related active complexes, [RuCl2(DMSO)2(Biim)] and [RuCl3(DMSO)(Biim)] have been tested; the latter is more cytotoxic against selected human cancer cell lines than the former.
(a) What is the oxidation state of the ruthenium in each of the four complexes?
(b) Suggest how each of the ligands Im, Ind and Biim coordinates to ruthenium.
(c) Draw the structures of possible isomers of each complex.
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Lets begin by answering each part of the question a Oxidation state of the ruthenium in each of the four complexes 1 HImRuCl4imDMSO To find the oxidat...View the full answer
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