(a) Deduce Gibbs-Duhem equation. (b) The excess Gibbs energy of a binary liquid mixture at constant temperature...

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(a) Deduce Gibbs-Duhem equation.

(b) The excess Gibbs energy of a binary liquid mixture at constant temperature and pressure is given by \[ \frac{G^{\mathrm{E}}}{R T}=\left(-2.6 x_{1}-1.8 x_{2}\right) x_{1} x_{2} \]
Show that the expression satisfies the Gibbs-Duhem equation.

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