Acetic acid vapor dimerizes according to 2A 1 A 2 . Assume that no higher-order associations

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Acetic acid vapor dimerizes according to 2A1 ⇆ A2. Assume that no higher-order associations occur. Supposing that a value for Ka is available, and that the monomers and dimers behave as an ideal gas, derive an expression for yA1 in terms of P and Ka. Then develop an expression for PV/noRT in terms of yA1, where no is the superficial number of moles neglecting dimerization. Write no /nT in terms of yA1 where nT = n1 = n2.

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