Compute the standard heat of reaction for each of the following reactions taking place at 298.15 K
Question:
Compute the standard heat of reaction for each of the following reactions taking place at 298.15 K in dilute aqueous solution at zero ionic strength.
(a) D-Glucose + ATP2− → D-Glucose 6-phosphate− + ADP−
(b) D-Glucose 6-phosphate− → D-Fructose 6-phosphate−
(c) D-Fructose 6-phosphate− + ATP2− → D-Fructose 1,6-biphosphate2− + ADP−
(d) D-Glucose + 2 ADP− + 2H2 PO−4 + 2 NAD+ → 2 Pyruvate−+ 2 ATP2− + 2 NADH + 4H+ + 2H2O
(e) D-Glucose + 2 ADP− + 2H2 PO−4 → 2 Lactate− + 2 ATP2−+ 2H+ + 2H2O
(f) D-Glucose + 2 ADP− + 2H2 PO−4 → 2CO2 + 2 Ethanol + 2 ATP2− + 2H2O
(g) 2 NADH + O2 + 2H+ → 2 NAD+ + 2H2O
(h) ADP− + H2 PO−4 →ATP2− + H2O
(i) 2 NADH + 2 ADP− + 2H2 PO−4 + O2 + 2H+ → 2 NAD+ + 2 ATP2− + 4H2O
(j) D-Fructose + 2 ADP− + 2H2 PO−4 → 2CO2 + 2 Ethanol +2 ATP2− + 2H2O
(k) D-Galactose + 2 ADP− + 2H2 PO−4 → 2CO2 + 2
(l) Ethanol + 2 ATP2− + 2H2O NH+4 + L-aspartate− + ATP2− → L-asparagine + ADP− + H2 PO−4
Step by Step Answer:
Introduction To Chemical Engineering Thermodynamics
ISBN: 9781259696527
8th Edition
Authors: J.M. Smith, Hendrick Van Ness, Michael Abbott, Mark Swihart