One method for the manufacture of synthesis gas depends on the vapor phase catalytic reaction of methane

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One method for the manufacture of synthesis gas depends on the vapor phase catalytic reaction of methane with steam according to the equation CH4 + H2O ⇆ CO + H2. The only other reaction which ordinarily occurs to an appreciable extent is the water-gas shift reaction. Gibbs energies and enthalpies for the problem are tabulated below in kJ/mol.CH4 HO CO CO AH , (600 K) -83.22 -244.72 -110.16 -393.80 , (1300 ) -91.71 -249.45 -113.85 -395.22 AG%, (600

Compute the equilibrium compositions based on a 1:1 feed ratio at 600 K and 1300 K and 1 bar and 100 bars.

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