The k ij for the pentane + acetone system has been fitted to a single point in

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The kij for the pentane + acetone system has been fitted to a single point in problem P15.6. Generate a P-x-y diagram at 312.75 K.


Data from problem P15.6

A vapor mixture of CO2 (1) and i-butane (2) exists at 120°C and 2.5 MPa. Calculate the fugacity of CO2 in this mixture across the composition range using

(a) The virial equation for mixtures 

(b) The Peng-Robinson equation

(c) The virial equation for the pure components and an ideal mixture model.

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