Question: (a) Suppose you could find a solution (r 1 ,r 2 , ..., r z ) to the Schrdinger equation (Equation 5.37), for the
(a) Suppose you could find a solution Ψ (r1,r2, ..., rz) to the Schrödinger equation (Equation 5.37), for the Hamiltonian in Equation 5.36. Describe how you would construct from it a completely symmetric function, and a completely antisymmetric function, which also satisfy the Schrödinger equation, with the same energy. What happens to the completely antisymmetric function if Ψ (r1,r2, ..., rz) is symmetric in (say) its first two arguments (r1 ↔ r2)?
(b) By the same logic, show that a completely antisymmetric spin state for Z electrons is impossible, if Z > 2 (this generalizes Problem 5.10(a)).
Equation 5.36

Equation 5.37
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Problem 5.10(a)
(a) Prove it.
What does antisymmetry under 1 ↔ 2 tell you about the coefficients?
(5.36) 1x| = 507) (2207) 43-
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a where etc runs over all permutations of the arguments r 1 r 2 r Z with a sign for all ... View full answer
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