For an atom in a uniform magnetic field B 0 = B 0 Z, Equation 4.230 gives

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For an atom in a uniform magnetic field B0 = B0 Ẑ, Equation 4.230 gives

where Lz and Sz refer to the total orbital and spin angular momentum of all the electrons.
(a) Treating the terms involving B0 as a perturbation, compute the shift of the ground state energy of a helium atom to second order in . Assume that the helium ground state is given by

where Ψ100 refers to the hydrogenic ground state (with Z = 2).
(b) Use the results of Problem 7.49 to calculate the magnetic susceptibility of helium. Given a density of 0.166kg/m3, obtain a numerical value for the susceptibility.

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Introduction To Quantum Mechanics

ISBN: 9781107189638

3rd Edition

Authors: David J. Griffiths, Darrell F. Schroeter

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