A mixture of methanol (a) and ethyl acetate (b) exhibits an azeotrope at 55C. Their saturation pressures
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A mixture of methanol
(a) and ethyl acetate
(b) exhibits an azeotrope at 55°C. Their saturation pressures are 68.8 and 46.5 kPa, respectively. The liquid-phase nonideality can be described by the two-suffi x Margules equation, with A = 2900 J/mol. What is the pressure and composition of the azeotrope? Does this mixture form a maximum-boiling azeotrope or a minimum-boiling azeotrope? Explain.
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