Consider the three constitutional isomers of dioxane (C 4 H 8 O 2 ): One of these

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Consider the three constitutional isomers of dioxane (C4H8O2):

1,3-dioxane 1,2-dioxane 1,4-dioxane


One of these constitutional isomers is stable under basic conditions as well as mildly acidic conditions and is therefore used as a common solvent. Another isomer is only stable under basic conditions but undergoes hydrolysis under mildly acidic conditions. The remaining isomer is extremely unstable and potentially explosive. Identify each isomer, and explain the properties of each compound.

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Organic Chemistry

ISBN: 978-0470917800

1st edition

Authors: David R. Klein

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