Explore the consequences of replacing the equation of state of a perfect gas by the van der
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Explore the consequences of replacing the equation of state of a perfect gas by the van der Waals equation of state for the pressure-dependence of the molar Gibbs energy. Proceed in three steps. First, consider the case when a=0 and only repulsions are significant. Then consider the case when b=0 and only attractions are significant. For the latter, you should consider making the approximation that the attractions are weak. Finally, explore the full expression by using mathematical software. In each case plot your results graphically and account physically for the deviations from the perfect gas expression.
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Related Book For
Physical Chemistry Thermodynamics And Kinetics
ISBN: 9781464124518
10th Edition
Authors: Peter Atkins, Julio De Paula
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