The mass to use in the expression for the vibrational frequency of a diatomic molecule is the

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The mass to use in the expression for the vibrational frequency of a diatomic molecule is the effective mass µ = mAmB/(mA + mB), where mA and mB are the masses of the individual atoms. The following data on the infrared absorption wavenumbers (in cm−1) of molecules are taken from Spectra of diatomic molecules, G. Herzberg, van Nostrand (1950):

Calculate the force constants of the bonds and arrange them in order of increasing stiffness.

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Physical Chemistry

ISBN: 9780716787594

8th Edition

Authors: Peter Atkins, Julio De Paula

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