Question: Blank solutions were monitored for vanadium as 51V+ 51 V + using inductively coupled plasma-mass spectrometry with the following results. a. Is the HClHCl used

Blank solutions were monitored for vanadium as 51V+ 51V+ using inductively coupled plasma-mass spectrometry with the following results.

Blank solution Water 2% HC12% HC1 5% HCI5% HC1 10% HC110% HCI

a. Is the HClHCl used to prepare the blank solutions contaminated with vanadium?

b. Would monitoring 50V+50V+ be a better alternative?

c. What acid should be used in place of HClHCl?

Blank solution Water 2% HC12% HC1 5% HCI5% HC1 10% HC110% HCI No interference removal 0.000.00 88.888.8 205205 418418 Apparent vanadium concentration (ppb) He collision cell 0.100.10 0.390.39 0.870.87 1.821.82 Dynamic reaction cell NH3NH3 0.000.00 0.000.00 0.000.00 0.000.00

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