Question
A solution of sodiumhydroxide (NaOH) was standardized against potassium hydrogenphthalate (KHP). A known mass of KHP was titrated with the NaOH solution until a light
A solution of sodiumhydroxide (NaOH) was standardized against potassium hydrogenphthalate (KHP). A known mass of KHP was titrated with the NaOH solution until a light pink colour appeared singphenolpthalein indicator. Using the volume of NaOH requiredto neutralize KHP and the number of moles of KHP titrated, the concentration of the NaOH solution was calculated.
A vinegar (acetic acid) solution of unknown concentration wastitrated to the light pink endpoint with the standardized NaOHsolution. The molarity and weight\volume % of the vinegar solution were calculated. A vitamin C (ascorbic acid) tablet was dissolved in approximately50 mL of distilled water and titrated with the standardized NaOH solution. From the results of this titration, the mg of ascorbic acid in thetablet was calculated.
Molecular formulas:
Potassium hydrogen phthalate: HKC8H4O4
Acetic acid: C2H4O2
Ascorbic acid: C6H8O6
Assume that all 3 acids are monoprotic acids.
Mass of KHP used forstandardization (g) 0.5591
Volume of NaOH required to neutralize KHP (mL) 13.39
Volume of vinegar sample titrated (mL) 5.00
Volume of NaOH required to neutralize vinegar in(mL) 8.38
Molecular weight of ascorbic acid (g/mol) 176.1271
Volume of NaOH required to neutralize ascorbic acid in Vitamin Ctablet (mL) 13.56
A. What is the Molecular Weight of KHP (HKC8H4O4) in g/mol?
B. How many moles of KHP were used in the standardization of the NaOH solution?
C. Calculate the concentration of NaOH solution in (mol/L).
D. Calculate the molarity of the vinegar solution (mol/L).
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