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0. Consider the solubility equilibrium of calcium hydroxide: [ mathrm{Ca}(mathrm{OH})_{2} ext { } quad mathrm{Ca}^{2+}+2 mathrm{OH}^{-} ] And ( Delta_{r} H^{circ}=-17.6 mathrm{~kJ} mathrm{~mol}^{-1} ) and
0. Consider the solubility equilibrium of calcium hydroxide: [ mathrm{Ca}(mathrm{OH})_{2} ext { } quad mathrm{Ca}^{2+}+2 mathrm{OH}^{-} ] And ( Delta_{r} H^{circ}=-17.6 mathrm{~kJ} mathrm{~mol}^{-1} ) and ( Delta_{r} S^{circ}=-158.3 mathrm{~J} mathrm{~K}^{-1} mathrm{~mol}^{-1} ). A saturated calcium hydroxide solution contains ( 1.2 imes 10^{-2} mathrm{M}left[mathrm{Ca}^{2+} ight] ) and ( 2.4 imes 10^{-2}left[mathrm{OH}^{-} ight] )at ( 298 mathrm{~K} ), which are at equilibrium with the solid in the solution. The solution is quickly heated to ( 400 mathrm{~K} ). Calculate the ( Delta_{mathrm{r}} mathrm{G} ) at ( 350 mathrm{~K} ) with the concentrations given, and state whether calcium hydroxide will precipitate or be more soluble upon heating. (10 marks)
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