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1 . A tubular reactor is to be designed for production of butadiene from butene by the gas phase reaction, ! ! # +

1. A tubular reactor is to be designed for production of butadiene from butene by the gas phase reaction,
!"!# + $
The composition of the feed is 10 moles of steam per mole of butene and no butadiene and hydrogen. The reactor
operates at 2 atm with an inlet temperature of 922 K. The reaction follows the first order, irreversible equation for
which the reaction rate constant as a function of temperature is
T, K 922900877855832
k, h-1114.92.040.850.32
The heat of reaction may be taken as constant and equal to %=263.6/ and &'& =1.2/.
a) What would be the volume required to achieve 20% conversion if the reactor operated isothermally at 922 K
with a butene+steam feed rate of 22 lbmol/h.
b) Calculate the reactor volume to achieve 20% conversion of butene for adiabatic operation if the feed rate is 2
lbmol butene/h and 20 lbmol steam/h.

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