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( 1 ) In the electrolytic refining of nickel the anode is a Cu - Ni alloy with 8 0 atom % N i ,

(1) In the electrolytic refining of nickel the anode is a Cu-Ni alloy with 80 atom %Ni, whereas the cathode is pure nickel.
(a) Calculate the reversible emf at 25C when the alloy is assumed to be an ideal solid solution.
(b) In practice both Ni and Cu dissolve from the anode. The anolyte is withdrawn and copper is removed by cementation as pure Cu on Ni sponge. Calculate the equilibrium ratio CuNi in the purified electrolyte at 25C, when the ionic activities are taken equal to their molalities.
(c) In practice the applied cell voltage is 2.0 and the cathodic current efficiency is 95 percent. Calculate the electric energy consumption in kilowatthours per kilogram of refined nickel.
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