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( 1 ) In the electrolytic refining of nickel the anode is a Cu - Ni alloy with 8 0 atom % N i ,
In the electrolytic refining of nickel the anode is a CuNi alloy with atom whereas the cathode is pure nickel.
a Calculate the reversible emf at when the alloy is assumed to be an ideal solid solution.
b In practice both and Cu dissolve from the anode. The anolyte is withdrawn and copper is removed by cementation as pure on sponge. Calculate the equilibrium ratio in the purified electrolyte at when the ionic activities are taken equal to their molalities.
c In practice the applied cell voltage is and the cathodic current efficiency is percent. Calculate the electric energy consumption in kilowatthours per kilogram of refined nickel.
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