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[ 1 ] The irreversible gas - phase reaction of S O 2 to S O 3 is carried out in a PFR working at

[1] The irreversible gas-phase reaction of SO2 to SO3 is carried out in a PFR working at a total pressure of
10atm. The inlet feed includes a 100-fold stoichiometric excess of O2(i.e.,FO2FSO2=50) to assure
complete conversion of SO2, indicating negligible changes in volumetric flow rate and total pressure
along the PFR. Also, the inlet feed has a volumetric flow rate of 50m3min at 800K and 10atm.
SO2+12O2SO3
Though the reaction rate is -rSO2=kPSO2PO2, it can be simplified into -rSO2~~k'PSO2 when PO2 is in
large excess. From experiments, the partial pressure of SO3(pSO3) was recorded along the length of the
reactor (z), as shown below. How would you obtain the reaction order of SO2() from the plot of pSO3
vs.z? Use the linearized form of the equation obtained from the information of this plot. [4 pts]
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