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10.9 The genus Aspergillus includes several hundred species of mold, which collectively produce a large number of natural products. Many of these natural products have

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10.9 The genus Aspergillus includes several hundred species of mold, which collectively produce a large number of natural products. Many of these natural products have been found to possess interesting biological properties. Two of these natural products were both synthesized from a common tricyclic precursor (compound 4 below) with an intricate shape. Tricyclic compound 4 was made from tyclic compound 1 using AIBN (which is further explored in Problem 10.30) and n-Buy SH to start a radical cyclization reaction. Draw a mechanism for the cyclization step in which bicyclic intermediate 2 is converted into tricyclic intermediate 3. AIBN n-Bunkt OEt ETO OEI OEt EIO 3

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