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2. Data for the gas-phase dissociation of sulfuryl chloride, SO,Cl, into chlorine, Cl, and sulfur dioxide, so, at 279.2 C are presented below. The

2. Data for the gas-phase dissociation of sulfuryl chloride, SO2Cl2 into chlorine, Cl2 and sulfur dioxide, SO2 at 279.2 °C are presented below. The total pressure method was employed to follow the course of the reaction. Under constant volume conditions the results were as follows: t(min) 3.4 15.Z 28.1 411 54.5 68.3 82.4 96.3 Hg) 323 325 335 345 355 365 375385 395 (a) What reaction order do these data suggest? (The (b) Using the results from part (a), design a PFR to conversion is 100% at infinite time). achieve 75% conversion of a feed of 1 gmol/min of an equimolar feed of So2Cl2 and inerts at 279.2 °C 

2. Data for the gas-phase dissociation of sulfuryl chloride, SO,Cl, into chlorine, Cl, and sulfur dioxide, so, at 279.2 C are presented below. The total pressure method was employed to follow the course of the reaction. Under constant volume conditions the results were as follows: (min) 28.1 41.1 54.5 3.4 15.7 96.3 68.3 82.4 (mm 345 Hg) 395 323 325 335 355 365 375 385 (a) What reaction order do these data suggest? (The conversion is 100% at infinite time). (b) Using the results from part (a), design a PFR to achieve 75% conversion of a feed of 1 gmol/min of an equimolar feed of SO,CI, and inerts at 279.2 C.

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