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2 . 7 . Aniline is produced by the hydrogenation of nitrobenzene. A small amount of cyclo - hexylamine is produced as a by -
Aniline is produced by the hydrogenation of nitrobenzene. A small amount of cyclohexylamine is produced as
a byproduct. The reactions are:
Nitrobenzene is fed to the reactor as a vapor, with three times the stoichiometric quantity of hydrogen. The
conversion of the nitrobenzene to all products is and the selectivity for aniline is
The unreacted hydrogen is separated from the reactor products and recycled to the reactor. A purge is taken
from the recycle stream to maintain the inerts in the recycle stream below The fresh hydrogen feed is
pure, with the remainder being inerts. All percentages are molar.
For a feed rate of kmo of nitrobenzene, calculate:
a The fresh hydrogen feed
b The purge rate required
c The composition of the reactor outlet stream
Use Proll to simulate the textbook problem Assume feed
and hydrogen are available at Assume separation is done
with a flash drum at The conditions at the reactor is
C & Ignore pressure drops for this exercise.
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