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2. Consider the global NO formation reaction: N2+O24k62NOdtd[NO]=k6[N2]N1[O2]r Along with a thermal mechanism: (Zeldovich) (1) O+N2NO+NEo=315kJ/mol (2) N+O2NO+OE=26kJ/mol Forward reaction (1) is endothermic and due
2. Consider the global NO formation reaction: N2+O24k62NOdtd[NO]=k6[N2]N1[O2]r Along with a thermal mechanism: (Zeldovich) (1) O+N2NO+NEo=315kJ/mol (2) N+O2NO+OE=26kJ/mol Forward reaction (1) is endothermic and due to the high Ea requires high temperatures ( 1800K) to proceed and is very slow. From above two reactions, using basic arguments, derive the following expression for the "initial" NO reaction rate for the global reaction: dtd[NO]=kG2kf1RTKPrf[N2][O2]12 2. Consider the global NO formation reaction: N2+O24k62NOdtd[NO]=k6[N2]N1[O2]r Along with a thermal mechanism: (Zeldovich) (1) O+N2NO+NEo=315kJ/mol (2) N+O2NO+OE=26kJ/mol Forward reaction (1) is endothermic and due to the high Ea requires high temperatures ( 1800K) to proceed and is very slow. From above two reactions, using basic arguments, derive the following expression for the "initial" NO reaction rate for the global reaction: dtd[NO]=kG2kf1RTKPrf[N2][O2]12
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