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3 . 1 0 . When an insoluble bubble rises in a deep pool of liquid, its volume increases according to the ideal gas

3.10". When an insoluble bubble rises in a deep pool of liquid, its volume increases according to the ideal gas law. However, when a soluble bubble rises from deep submersion, there is a competing action of dissolution that tends to reduce size. Under practical conditions, it has been proved (Rice 1982) that the mass transfer coefficient (kc) for spherical particles (or bubbles) in free fall (or free-rise) is substantially constant. Thus, for sparingly soluble bubbles released from rest, the following material balance is applicable:
d(C*(43)R3)dt=-kc*C***4R2(t)
where C=PRgT is the (ideal) molar density of gas, C** is molar solubility of gas in liquid, and R(t) is the changing bubble radius. The pressure at a distance z from the top liquid surface is P=PA+Lgz, and the rise velocity is assumed to be quasi-steady and follows the intermediate law according to Rice and Littlefield (1987) to give a linear relation between speed and size
dzdt=U=(2g15v12)23*2R(t)=*R(t):
note 0 for rising bubble.
where g is gravitational acceleration, and v is liquid kinematic viscosity.
a. Show that a change of variables allows the material balance to be written as
null
RdRdP+13R2P=-P
where
=kcRgTC**Lg0 since 0
b. Solve the equation in part (a) subject to the initial condition R(o)=R0,P(o)=Po=PA+gz0 and prove that
PP0=(R02+3R2+3)32
Now, find the expression for the time required to cause a soluble bubble to completely disappear (R0).
Answer: =[P0R0]kcC**RgT;tf=[1+29(R02)]
Only want b time expressions ! Please show how to get them !
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