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3. Nucleation Following is an expression for the Gibbs free energy required to nucleate a spherical solid of radius r in a liquid at
3. Nucleation Following is an expression for the Gibbs free energy required to nucleate a spherical solid of radius r in a liquid at a temperature T below Tm. A G = - 3 S 141 |r (61 - 6) + 4r 8se G (a) Derive the value of the radius (r*) above which the spherical solid will nucleate. (b) What will happen to spherical solids that form with a radius smaller than r*? (c) Find AG*, which is the value of AG at r*. (d) What property could you change to reduce the critical radius of nucleation, and how would you change it? Assume ysl is held constant. (Hint: consider the expression for the Gibbs free energy for the nucleation of a solid that contains the latent heat of fusion, L)
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