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3. You're looking to make a polymer from the following monomers: A: HAN You're looking at the following recipes: NH #1) 1 mol of A
3. You're looking to make a polymer from the following monomers: A: HAN You're looking at the following recipes: NH #1) 1 mol of A and 1 mol of B, B: #2) 1 mol of A and 0.5 mol each of B and C (mixed with each other before mixing with A), or HO OH o= #3) 1 mol of A and 1 mol of C. C: Would these polymers grow via radical polymerization or condensation polymerization? HO O . Would they grow in a step growth or a chain growth manner? Rank the expected melting temperatures for the recipes, highest to lowest. (Hint: think of the chain-chain interactions that would take place, and how uniform/evenly spaced each of the amide bonds are. The more amide bonds and the more uniform the spacing (chain-chain interaction), the higher the melting temp) What are the common names of these polymers? (You'll be extra cool if you make a distinction in the type for #1 and #3). 4. Look up the molecular structure of polycaprolactone and polyglycolide. What is the key difference between the two? Without looking up the numbers, predict which will have higher Tg and Tm. Check your predictions. Where do these differences come from
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