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4 0 p . Consider the network of 1 s t order reactions given by All four reactions are irreversible and have the same rate

40p. Consider the network of 1st order reactions given by
All four reactions are irreversible and have the same rate constant, k. A cyclic system consisting of irreversible
reactions with identical rate constants would be extremely unlikely to occur, but it's a nice training problem).
(a)5 p. Write this set of reactions in matrix form (i.e.A??=0?)
(b)5 p. Write the rate equations in terms of the reaction rates in matrix form using the stoichiometric matrix
(i.e.,dC??dt=??Tr?).
(c)10 p. Write the rate equations in terms of a matrix of rate constants and a vector of concentrations (i.e.,
). How are the matrices ??T and M? related?
(d)15 p. Find an analytical solution to the rate equations for the initial condition
CA1(t=0)=Co and CA2(t=0)=CA2(t=0)=CA1(t=0)=0 using the matrix method discussed in class.
(e)5p. If there are iA1 molecules, jA2 molecules, and kA3 molecules in the system at time t, what is the
probability that at some very short time later (t+t) there are (j+1)A2 molecules? What is the probability
that there are (j-1 molecules? What is the probability that there are jA2 molecules?
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