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5 . 4 The equilibrium adsorption of benzene vapor on a certain activated charcoal at 3 3 . 3 C is reported as follows: (

5.4 The equilibrium adsorption of benzene vapor on a certain activated charcoal at 33.3C is
reported as follows:
(a) A nitrogen-benzene vapor mixture containing 1.0% benzene by volume is to be passed
countercurrently at the rate 100ft3min(4.7210-2m3s) to a moving stream of the activated
charcoal so as to remove 95% of the benzene from the gas in a continuous process. The entering
charcoal contains 15cm3 benzene vapor (at STP) adsorbed per gram charcoal. The temperature and
total pressure are to be maintained at 33.3C and 1stdatm, respectively, throughout. Nitrogen is not
adsorbed. What is the least amount of charcoal which can be used per unit time? If twice as much is
used, what will be the concentration of benzene adsorbed upon the charcoal leaving?
(b) Repeat part (a) for a cocurrent flow of gas and charcoal.
(c) Charcoal which has adsorbed upon it 100cm3(at STP) tenzene vapor per gram is to be
stripped at the rate 100lbh(45.4kgh) of its benzene content to a concentration of 55cm3
adsorbed benzene per gram charcoal by continuous countercurrent contact with a stream of pure
nitrogen gas at 1 std atm. The temperature will be maintained at 33.3C. What is the minimum rate
of nitrogen flow? What will be the benzene content of the exit gas if twice as much nitrogen is fed?
What will be the number of stages? Ans.: 3 theoretical stages.
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