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6. In methyl alcohol solution (CH3OH), bromine adds to ethylene to yield not only ethylene bromide but also Br CH2CH2 OCH3. How can you
6. In methyl alcohol solution (CH3OH), bromine adds to ethylene to yield not only ethylene bromide but also Br CH2CH2 OCH3. How can you account for this? Write equations for all 7 Give the structure of the alkene that yields on ozonolysis: (a) CH3CH2CH2CHO and HCHO (b) CH3-CH(CH3)-CHO and CH3CHO (c) Only CHICO-CH (d) CH, CHO and HCHO and OHC CH-CHO (e) What would each of these alkenes yield upon cleavage by KMnO4 ? 8. Describe simple chemical tests that would distinguish between: (a) 2-chloropentane and n-heptane (b) 2-hexene and tert-butyl bromide (c) isobutane and isobutylene (d) allyl bromide and 1-hexene (e) sec-butyl alcohol and n-heptane (f) 1-octene and n-pentyl alcohol (g) tert-pentyl alcohol and 2,2-dimethylhexane (h) n-propyl alcohol and allyl alcohol (CH2=CHCHOH) Tell exactly what you would do and see. (Qualitative elemental analysis is a simple chemical test; degradation 9. A hydrocarbon, A, adds one mole of hydrogen in the presence of a platinum catalyst to form n-hexane. When A is oxidi/ed vigorously with KMnO4, e single carboxylic acid, containing three carbon atoms, is isolated. Give the structure and name of A. Show your reasoning, including equations for all reactions.
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