Answered step by step

Verified Expert Solution

Link Copied!

Question

1 Approved Answer

Posted on Nov 11, 2020

7-8 The chiral Mn complex below undergoes racemization according to the equation shown. Mn PhMe/25 C PPH3 PPH3 Ph3P NO NO NO Ph t1/2

7-8 The chiral Mn complex below undergoes racemization according to the equation shown. Mn PhMe/25 C PPH3 "PPH3 Ph3P" NO NO NO Ph t1/2 = 21 min. 1/[PPh3] Ph Ph Rate x Propose a mechanism that is consistent with the rate being affected inversely by the concentration of PPh;.

Step by Step Solution

★★★★★

3.39 Rating (168 Votes )

There are 3 Steps involved in it

Step: 1

The compound MnNOCOPhPPh3 represent prototypes of configurationally labile complexes Solutions of bo... blur-text-image

Get Instant Access to Expert-Tailored Solutions

See step-by-step solutions with expert insights and AI powered tools for academic success

Step: 2

Step: 3

Ace Your Homework with AI

Get the answers you need in no time with our AI-driven, step-by-step assistance

Get Started

Recommended Textbook for

Organic Chemistry

Authors: L. G. Wade Jr.

8th edition

321768418, 978-0321768414

More Books

Students also viewed these Chemistry questions

Question

★★★★★

Propose a structure that is consistent with each set of 1H NMR data. IR data is provided for some compounds. (a) (b) (c) (d) (e) (f) (g) (h) (i) (j) (k) (l) (m) C4H1OO 6 (ppm) Splitting 1.28 1.35...

Answered: 1 week ago

Question

★★★★★

Propose a structure that is consistent with each of the following 1 H NMR spectra. In each case, the molecular formula is provided. (a) (b) (c) (d) (e) (f) Proton NMR C,H,,0 i ppm Integration Values...

Answered: 1 week ago

Question

★★★★★

Propose a mechanism that shows why p-chlorotoluene reacts with sodium hydroxide at 350 C to give a mixture of p-cresol and m-cresol.

Answered: 1 week ago

Question

★★★★★

An impure sample (0.70 g) of potassium carbonate (K2CO3) is dissolved in enough water to make 200.0 mL of solution A. A 20.00 mL aliquot of solution A is taken and put into an Erlenmeyer flask. To...

Answered: 1 week ago

Question

★★★★★

In Problem, find a standard form for the absorbing Markov chain with the indicated transition matrix. D4000 C3011 B310 .1 A0008

Answered: 1 week ago

Question

★★★★★

The same community college from Problem 9 has 7656 students currently enrolled in classes. To gain the students opinions about an upcoming building project, the college president wishes to obtain a...

Answered: 1 week ago

Question

★★★★★

In a hypothesis test, what (a) is the relationship between the power of a test and the probability of making a Type II error? (b) does it mean when the power is small at a particular value of the...

Answered: 1 week ago

Question

★★★★★

An investor requires a return of 12 percent. A stock sells for $25, it pays a dividend of $1, and the dividends compound annually at 7 percent. Will this investor find the stock attractive? What is...

Answered: 1 week ago

Question

★★★★★

Let f ( x ) = x e x . ( a ) Find the largest interval of the form [ a , ) for which f is increasing. ( b ) Restrict the domain of f to be the interval you found in part a ) . Let W = f - 1 be the...

Answered: 1 week ago

Question

★★★★★

Pet Emporium had a robbery on the weekend in which a large amount of inventory was taken. The loss is covered completely by insurance. A physical inventory count determined that the cost of the...

Answered: 1 week ago

Question

★★★★★

in details please to understand the steps..thank you 16:547 learn-eu-central-1-prod-fleet01-xythos.s3-eu-central-1.a Omar Inc. manufactures an advanced swim fin for scurba divers. Management is now...

Answered: 1 week ago

Question

★★★★★

The Capacity Factor average for solar panels is 24.9%. This is approximately 6 hours per day of power production on average across the year. For a 100 MW (mega-watt) plant how much power (MWh,...

Answered: 1 week ago

Question

★★★★★

Use the link given, to complete the lab below. The link is, https://phet.colorado.edu/en/simulations/wave-interference Lab: 2-Point Interference 25 Purpose: To test the equations for 2-Point...

Answered: 1 week ago

Question

★★★★★

Zuma is deciding between a 3 0 year and 1 5 year mortgage. He plans to purchase a $ 4 0 0 , 0 0 0 and has decided to do a 2 0 % downpayment so he doesn't have PMI. He expects property taxes to be $ 3...

Answered: 1 week ago

Question

★★★★★

An ANOVA is run looking at the effect of water, sun, and water*sun on plant growth. Given the partial output below, what conclusion would you draw about the relationship of these variable(s) on plant...

Answered: 1 week ago

Question

★★★★★

Sta. Elena Winery sells 100,000 gallons of wine a year. It sells 10% of its wine in barrels, 60% in jugs, and 30% in 1-liter bottles. Its base selling price is $2 per gallon in barrels. The selling...

Answered: 1 week ago

Question

★★★★★

On May 1, 2017, Herron Corp. issued $600,000,9%,5-year bonds at face value. The bonds were dated May 1, 2017 and pay interest annually on May 1. Financial statements are prepared annually on December...

Answered: 1 week ago

Question

★★★★★

Dawson Companys balance sheet information at the end of 2019 and 2020 is as follows: Additional information: The company did not issue any common stock during 2020. Required : Next Level Fill in the...

Answered: 1 week ago

Question

★★★★★

An enolate is a very strong nucleophile. Bromine is a strong electrophile, so it can react with much weaker nucleophiles. Give mechanisms for the reactions of bromine with cyclopentene and with...

Answered: 1 week ago

Question

★★★★★

Propose a mechanism for the crossed Claisen condensation between ethyl acetate and ethyl benzoate.

Answered: 1 week ago

Question

★★★★★

A student synthesized Compound 1 (below). To purify the compound, he extracted it into aqueous base and then acidified the solution to protonate the acid so that he could extract it back into ether....

Answered: 1 week ago

Question

★★★★★

LaCrosse Technology is one of many manufacturers of atomic clocks. It makes an atomic digital watch that is radio-controlled and that maintains its accuracy by reading a radio signal from a WWVB...

Answered: 1 week ago

Question

★★★★★

For the following normal distributions with parameters as specified, calculate the required probabilities: a. m 5, s 2; calculate P(0 x 8). b. m 5, s 4; calculate P(0 x 8). c. m 3, s 2;...

Answered: 1 week ago

Question

★★★★★

Canine Crunchies Inc. (CCI) sells large bags of dog food to warehouse clubs. CCI uses an automatic filling process to fill the bags. Weights of the filled bags are approximately normally distributed...

Answered: 1 week ago

Previous Question Next Question