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8 . 7 The Redlich - Kwong equation of state is given by p = R T v - b - a v ( v

8.7 The Redlich-Kwong equation of state is given by
p=RTv-b-av(v+b)T2
where R= the universal gas constant =0.518kJkgK,T= absolute temperature (K),p= absolute pressure (kPa), and v= the volume of a kg of gas (m3kg). The parameters a and b are calculated by
a=0.427R2Tc2.5pc,b=0.0866RTcpc
where pc= critical pressure (kPa) and Tc= critical temperature (K). As a chemical engineer, you are asked to determine the amount of methane fuel (pc=4600kPa and Tc=191K) that can be held in a 3-m3 tank at a temperature of -40C with a pressure of 65,000kPa. Use a root-locating method of your choice to calculate v and then determine the mass of methane contained in the tank.

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