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9 . 5 The equation of state for helium gas may be written in the form p V m = R T ( 1 +

9.5 The equation of state for helium gas may be written in the form
pVm=RT(1+BVm) where B is a function of temperature only and
has the following values:
TK,10,20,30,40,50,60,70
B10-6m3mol-1,-23.3,-4.0,+2.4,+5.6,+7.6,+8.9,+9.8
Determine (a) the Boyle temperature, (b) the inversion temperature,
(c) the temperature drop when helium initially at 20K and 10atm
pressure expands into a very large empty vessel under conditions of
thermal isolation.
[For helium, CmV=32R.]
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